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21.
Tao Wang Dr. Yuzhou Wu Dr. Seah Ling Kuan Oliver Dumele Dr. Markus Lamla Dr. David Y. W. Ng Matthias Arzt Jessica Thomas Jan O. Mueller Prof. Dr. Christopher Barner‐Kowollik Prof. Dr. Tanja Weil 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(1):228-238
A disulfide intercalator toolbox was developed for site‐specific attachment of a broad variety of functional groups to proteins or peptides under mild, physiological conditions. The peptide hormone somatostatin (SST) served as model compound for intercalation into the available disulfide functionalization schemes starting from the intercalator or the reactive SST precursor before or after bioconjugation. A tetrazole–SST derivative was obtained that undergoes photoinduced cycloaddition in mammalian cells, which was monitored by live‐cell imaging. 相似文献
22.
A model for the mechanics of woven fabrics is developed in the framework of two-dimensional elastic surface theory. Thickness effects are modeled indirectly in terms of appropriate constitutive equations. The model accounts for the strain of the fabric and additional effects associated with the normal bending, geodesic bending, and twisting of the constituent fibers. 相似文献
23.
Ivan Dragičević Dr. Danijela Barić Dr. Borislav Kovačević Prof. Bernard T. Golding Dr. David M. Smith 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(16):6132-6143
Model studies of prebiotic chemistry have revealed compelling routes for the formation of the building blocks of proteins and RNA, but not DNA. Today, deoxynucleotides required for the construction of DNA are produced by reduction of nucleotides catalysed by ribonucleotide reductases, which are radical enzymes. This study considers potential non‐enzymatic routes via intermediate radicals for the ancient formation of deoxynucleotides. In this context, several mechanisms for ribonucleotide reduction, in a putative H2S/HS. environment, are characterized using computational chemistry. A bio‐inspired mechanistic cycle involving a keto intermediate and HSSH production is found to be potentially viable. An alternative pathway, proceeding through an enol intermediate is found to exhibit similar energetic requirements. Non‐cyclical pathways, in which HSS. is generated in the final step instead of HS., show a markedly increased thermodynamic driving force (ca. 70 kJ mol?1) and thus warrant serious consideration in the context of the prebiotic ribonucleotide reduction. 相似文献
24.
Experimental Evidence of Chemical Components in the Bonding of Helium and Neon with Neutral Molecules 下载免费PDF全文
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N-Heterocyclic carbene catalysed redox isomerisation with reduction about the carbonyl has been developed in the transformation of trienyl esters to tetrasubstituted benzaldehydes. The reaction proceeds in good to excellent yield, and in cases that provide 2,2′-biaryls, enantioselectivity is observed. Mechanistic studies demonstrate the intermediacy of a cyclohexenyl β-lactone, while implicating formation of the homoenolate as turnover limiting. 相似文献
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Application of ion mobility tandem mass spectrometry to compositional and structural analysis of glycopeptides extracted from the urine of a patient diagnosed with Schindler disease 下载免费PDF全文
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Journal of Mathematical Chemistry - Deficiency zero is an important network structure and has been the focus of many celebrated results within reaction network theory. In our previous paper... 相似文献
29.
We study the response of nonlinear wave systems in bounded domains at or near resonance. There are typically two qualitatively distinct types of response which may be observed relating to whether or not higher harmonics are themselves resonant. We introduce a variety of nonlinear model problems at or near resonance and study the subsequent response. We explain how the features of this problem such as the form of nonlinearity, boundary conditions, and the nature of spectrum play a fundamental role in the qualitative nature of the response. Numerical simulations are carried out to provide further explanation and comparison with analytic approximations. The results of this study provide a better understanding of the impact and interplay between nonlinear and boundary effects and thus in turn will contribute to providing new insights into various physically motivated problems in acoustics and other settings. 相似文献
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